{"created":"2023-06-20T15:59:07.175953+00:00","id":4151,"links":{},"metadata":{"_buckets":{"deposit":"77983cce-a481-48a7-9305-19208aebf8c4"},"_deposit":{"created_by":3,"id":"4151","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"4151"},"status":"published"},"_oai":{"id":"oai:minpaku.repo.nii.ac.jp:00004151","sets":["345:417"]},"author_link":["40"],"item_9_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1997-12-08","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"281","bibliographicPageStart":"249","bibliographicVolumeNumber":"22","bibliographic_titles":[{"bibliographic_title":"国立民族学博物館研究報告"},{"bibliographic_title":"Bulletin of the National Museum of Ethnology","bibliographic_titleLang":"en"}]}]},"item_9_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Synthetic materials are now frequently used in everyday life, and it\nis not rare to encounter such materials in art, ethnologic or historical\nmuseums, not only as a part of the collection (for example, modern art\nor plastic tools) , but also as a constituent of the products used for exhibition,\nstorage, or conservation purposes.\nIn this article, taking alkyd paints as an example, we have tried to improve\nupon an analytical method which can procure a maximum of information\nabout the nature of the medium and that of the synthetic organic\npigments possibly present, from a minimally small sample. Two\nchromatographic techniques were experimented with and compared:\nPGC (Pyrolysis-Gas Chromatography) and THM (Thermally assisted\nHydrolysis and Methylation) .\nThe results showed that these two techniques complement each\nother. A first analysis by PGC differentiates alkyd resins from other synthetic\nor natural products, and at the same time, it can detect a number\nof synthetic organic pigments (especially azo ones) . Then, a complementary\nanalysis by THM will give more accurate information about\nthe constituents of the alkyd resins, that is to say, the nature of the \npolyhydric alcohol, polybasic acid, and drying oil or fatty acids. It is interesting\nto note that, with both techniques, the presence of organic or inorganic\npigments does not affect the characterization of an alkyd\nmedium.\nWe expect to develop and apply, in the future, this analytical protocol\nto the characterization of synthetic materials generally encountered\nin museums, considering that PGC is a rapid and efficaceous method for\nthe characterization of thermoplastic resins and some synthetic organic\npigments, and THM for the characterization of resins which cannot be\neasily analysed by PGC.","subitem_description_type":"Abstract"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15021/00004143","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"国立民族学博物館"}]},"item_9_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00091943","subitem_source_identifier_type":"NCID"}]},"item_9_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0385-180X","subitem_source_identifier_type":"ISSN"}]},"item_9_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"園田, 直子"},{"creatorName":"ソノダ, ナオコ","creatorNameLang":"ja-Kana"},{"creatorName":"Sonoda, Naoko","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-11-19"}],"displaytype":"detail","filename":"KH_022_2_001.pdf","filesize":[{"value":"1.7 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KH_022_2_001.pdf","url":"https://minpaku.repo.nii.ac.jp/record/4151/files/KH_022_2_001.pdf"},"version_id":"9973bffc-4cfe-4841-9591-3c7b2dbe167d"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"アルキド絵具｜合成有機顔料｜熱分解ガスクロマトグラフィー｜反応熱分解を利用した(TMAH共存下における)熱分解ガスクロマトグラフイー","subitem_subject_scheme":"Other"},{"subitem_subject":"alkyd paints｜synthetic organic pigments｜PGC (pyrolysis-gas chromatography)｜THM (thermally assisted hydrolysis and methylaion)","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"合成素材の分析・識別法に関する基礎研究 : アルキド絵具を例として","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"合成素材の分析・識別法に関する基礎研究 : アルキド絵具を例として"},{"subitem_title":"Basic Study on the Analysis of Synthetic Materials in Museums : PGC and THM Applied to the Characterization of Alkyd Paints Containing Synthetic Organic Pigments","subitem_title_language":"en"}]},"item_type_id":"9","owner":"3","path":["417"],"pubdate":{"attribute_name":"公開日","attribute_value":"2010-02-16"},"publish_date":"2010-02-16","publish_status":"0","recid":"4151","relation_version_is_last":true,"title":["合成素材の分析・識別法に関する基礎研究 : アルキド絵具を例として"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T17:18:54.683591+00:00"}